Volume 79 in the venerable Organic Reactions series contains two chapters. The first addresses cross-coupling reactions of organotrifluoroborate salts, useful in the development of natural products, materials, and pharmacologically active substances.
This volume in the venerable Organic Reactions series contains three chapters focusing on the introduction or the removal of nitrogen from organic compounds. The first chapter features a classic chemical reaction for introducing nitrogen into organic compounds, namely the Schmidt Reaction.
Volume 82 describe reactions that involve one of the most common transformations in organic chemistry, namely, the pairwise combination of double bonded functional groups. The importance of this enormous family of reactions is a reflection of the spectacular diversity of precursors and products that can arise from appropriate modulation of reactivity of the partners and especially selection of reagents that dictate the outcome. The first chapter authored by Takeshi Takeda and Akira Tsubouchi describes the combination of carbonyl compounds in the presence of highly reactive, low valent titanium reagents in the classic McMurry reaction. The second chapter concerns the chemistry of highly-reactive, double-bonded functional groups, namely ketenes.
Allylic boron compounds have gained a prominent position as a truly practical class of synthetic reagents in the past twenty-five years. Their main application as a method for the stereoselective synthesis of homoallylic alcohols by allyl-transfer to carbonyl compounds is essentially unmatched.
The volumes of Organic Reactions are collections of chapters each devoted to a single reaction, or a definite phase of a reaction, of wide applicability. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure and the selection of experimental techniques. Numerous detailed procedures illustrate the significant modifications of each method. Includes tables that contain all possible examples of the reaction under consideration.
Each chapter of this reference presents examples of the reaction under consideration. Particular attention is paid to limitations, interfering influences, the effects of structure, and the selection of experimental techniques.
This series provides the most comprehensive and highly focused treatment of important organic reactions currently available. This volume in the prestigious series includes chapters covering two of the most fundamental processes in organic chemistry: oxidation and reduction.
This new volume in the venerable Organic Reactions series comprises two chapters written in part by the inventors of the unique and important name reactions discussed in these chapters.
The volumes of this series are collections of essays devoted to a single reaction or a definite phase of a reaction. This volume addresses the Peterson olefination reaction, the net reaction and tandem vicinal difunctionalization +gb+n-addition to +ga,b+n-unsaturated carbonyl substrates.
The volumes of Organic Reactions are collections of chapters each devoted to a single reaction, or a definite phase of a reaction, of wide applicability. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure, and the selection of experimental techniques. Numerous detailed procedures illustrate the significant modifications of each method. Includes tables that contain all possible examples of the reaction under consideration.
The volumes of Organic Reactions are collections of chapters each devoted to a single reaction, or a definite phase of a reaction, of wide applicability. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure, and the selection of experimental techniques. Numerous detailed procedures illustrate the significant modifications of each method. Includes tables that contain all possible examples of the reaction under consideration.
This series provides the most comprehensive and highly focused treatment of important organic reactions currently available. All volumes of Organic Reactions (including this one) are collections of chapters each devoted to a single reaction or a definitive phase of a reaction, of wide applicability.
Volume 76 in the venerable Organic Reactions series comprises three chapters that cover the ever-increasing emphasis of transition metal catalysis in organic synthesis. These three chapters represent some of the most important transformations that enable the construction of carbon-carbon bonds, heterocycles and carbon-heteratom bonds.
Ionic and Organometallic-Catalyzed Organosilane Reductions provides an up-to-date, comprehensive review of reductions with organosilanes. Both ionic and catalyst-mediated reaction types are included, with appropriate reference to reaction mechanisms where they have been elucidated.
The latest volume in this series for organic chemists in industry presents critical discussions of widely used organic reactions or particular phases of a reaction. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure and the selection of experimental techniques.
Volume 81 represents the confluence of two rare and important phenomena for chapters in the Organic Reactions series, namely, it is a single-chapter volume, and it contains a name reaction coauthored by the inventor. Of the 261 chapters published thus far, only seven have been of sufficient impact to appear as single-chapter volumes. The single chapter in this volume entitled "The Krapcho Dealkoxycarbonylation Reaction of Esters with a-Electron-Withdrawing Substituents" has been coauthored by A. Paul Krapcho together with Organic Reactions' long-time contributor Engelbert Ciganek. The "Krapcho Decarboxylation," as it is known in common parlance, is an extraordinarily useful alternative to the classical hydrolysis-decarboxylation of esters bearing a-electron-withdrawing substituents. This process replaces the strongly basic or acidic conditions normally required for ester saponification with the neutral cleavage of the ester group by a BAC2 mechanism through the combination of water and a dipolar aprotic solvent at high temperature. However, another popular variant involves the use of inorganic salts such as lithium chloride, sodium iodide, or sodium cyanide in a dipolar aprotic solvent which can open a second mechanistic pathway (dependent upon the ester) through BAL2 cleavage. Drs. Krapcho and Ciganek expertly outline the broad substrate scope of this reaction and identify the preferred conditions for various substrate classes. The 371 pages of tables containing all known examples of this simple but important transformation, together with the 1,908 references cited in this Chapter, are testimony to the synthetic usefulness of the Krapcho reaction.
The volumes of Organic Reactions are collections of chapters, each dedicated to a singled reaction or definitive phase of a reaction of wide applicability. The subject is presented from the preparative viewpoint & particular attention is given to limitations, interfering influences, effects of structure & the selection of experimental techniques.
The latest volume in this series presents critical discussions of widely used organic reactions or particular phases of a reaction. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure and experimental techniques.
The volumes of Organic Reactions are collections of chapters each devoted to a single reaction, or a definite phase of a reaction, of wide applicability. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure, and the selection of experimental techniques. Numerous detailed procedures illustrate the significant modifications of each method. Includes tables that contain all possible examples of the reaction under consideration.
The volumes of Organic Reactions are collections of chapters each devoted to a single reaction, or a definite phase of a reaction, of wide applicability. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure, and the selection of experimental techniques. Numerous detailed procedures illustrate the significant modifications of each method. Includes tables that contain all possible examples of the reaction under consideration.
The volumes of Organic Reactions are collections of chapters each devoted to a single reaction, or a definite phase of a reaction, of wide applicability. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure, and the selection of experimental techniques. Numerous detailed procedures illustrate the significant modifications of each method. Includes tables that contain all possible examples of the reaction under consideration.
The volumes of Organic Reactions are collections of chapters, each dedicated to a singled reaction or definitive phase of a reaction of wide applicability. The subject is presented from the preparative viewpoint & particular attention is given to limitations, interfering influences, effects of structure & the selection of experimental techniques.
This volume presents critical discussions of widely-used organic reactions or particular phases of a reaction. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure and the selection of experimental techniques.
The latest volume in this series for organic chemists in industry presents critical discussions of widely used organic reactions or particular phases of a reaction. The material is treated from a preparative viewpoint, with emphasis on limitations and the selection of experimental techniques.
A series of volumes composed of chapters devoted to important synthetic reactions. Each chapter in these volumes includes procedures illustrating the significant modifications of the chemical reaction as well as tables including pertinent examples.
Each chapter of this reference presents examples of the reaction under consideration. Particular attention is paid to limitations, interfering influences, the effects of structure, and the selection of experimental techniques.
The volumes of Organic Reactions are collections of chapters each devoted to a single reaction, or a definite phase of a reaction, of wide applicability. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure, and the selection of experimental techniques. Numerous detailed procedures illustrate the significant modifications of each method. Includes tables that contain all possible examples of the reaction under consideration.
The volumes of Organic Reactions are collections of chapters each devoted to a single reaction, or a definite phase of a reaction, of wide applicability. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure, and the selection of experimental techniques. Numerous detailed procedures illustrate the significant modifications of each method. Includes tables that contain all possible examples of the reaction under consideration.
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