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Synthesis and Structural Characterization of Arsinoamide and its Metal Complexes

Om Synthesis and Structural Characterization of Arsinoamide and its Metal Complexes

The phosphinoamide chemistry has attracted a considerable attention owing to the structural diversity of the associated complexes. To further understand the properties of the P-N bond, Ashby synthesized the compound [(Ph2P-NPh)Li(Et2O)] through the deprotonation reaction of the corresponding aminophosphine with nBuLi. X-ray diffraction analyses indicated the presence of Li-P bonds (2.684 and 3.004 Å). In addition, the P-N bond length (1.672(2) Å) was relatively smaller than that of a single bond (mean value of 1.70).

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  • Språk:
  • Engelska
  • ISBN:
  • 9783736970342
  • Format:
  • Häftad
  • Sidor:
  • 138
  • Utgiven:
  • 20. juni 2019
  • Mått:
  • 210x148x8 mm.
  • Vikt:
  • 172 g.
  Fri leverans
Leveranstid: 2-4 veckor
Förväntad leverans: 27. november 2024

Beskrivning av Synthesis and Structural Characterization of Arsinoamide and its Metal Complexes

The phosphinoamide chemistry has attracted a considerable attention owing to the structural diversity of the associated complexes. To further understand the properties of the P-N bond, Ashby synthesized the compound [(Ph2P-NPh)Li(Et2O)] through the deprotonation reaction of the corresponding aminophosphine with nBuLi. X-ray diffraction analyses indicated the presence of Li-P bonds (2.684 and 3.004 Å). In addition, the P-N bond length (1.672(2) Å) was relatively smaller than that of a single bond (mean value of 1.70).

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